Ethyl Acetate

Information pertaining to particular dangers for man and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EC"
in the latest valid version.
Has a narcotizing effect.
R 11 Highly flammable.
R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
R 36 Irritating to eyes.
R 68/20/21/22 Harmful: possible risk of irreversible effects through inhalation,
in contact with skin and if swallowed.
R 66 Repeated exposure may cause skin dryness or cracking.
R 67 Vapours may cause drowsiness and dizziness.

Classification system for Ethyl Acetate:
The classification was made according to the latest editions of the EU-lists, and expanded using company data and specialized literature.

Chemical characterization for Ethyl Acetate, ethyl ethanoate (EtOAc or EA):
CAS No. Description: 141-78-6	ethyl acetate
EINECS Number: 205-500-4	Xi, F; R 11-36-66-67
CAS No. :67-63-0	propan-2-ol
EINECS: 200-661-7	Xi, F; R 11-36-67
CAS: 67-56-1	methanol
EINECS: 200-659-6	T, F; R 11-23/24/25-39/23/24/25
CAS: 64-17-5	ethanol
EINECS: 200-578-6	F; R 11
Additional information:	For the wording of the listed risk phrases refer to section 16.
EU Number:	607-144-00-9

General Information for Ethyl Acetate, ethyl ethanoate (EtOAc or EA):
Form:	Fluid
Colour:	According to product specification
Odour:	Characteristic
Change in condition
Melting point/Melting range:	undetermined
Boiling point/Boiling range:	undetermined
Flash point:	not determined
Self ingnition temperature:	Product is not self-igniting.
Ignition temperature:	420°C
Danger of explosion:	Product is not explosive. However, formation of explosive air/vapour mixtures are possible.
Density:	Not determined
Solubility in / Miscibility with Water:	Not determined

Land transport ADR/RID (cross-border) for Ethyl Acetate:
ADR/RID class:	3 (F1) Flammable liquids.
Danger code (Kemler):	30
UN-Number:	1993
Packaging group:	II
Label:	3
Description of goods:	1992 FLAMMABLE LIQUID, TOXIC, N.O.S. (ETHYL ACETATE, METHANOL)
Limited quantities (LQ)	LQ7
Transport category	3
Tunnel restriction code	E
Remarks:	Limited quantitiy: 3 l inner packaging, 30 kg gross packaging unit
Maritime transport IMDG:
IMDG Class:	3
UN Number:	1993
Label:	3
Packaging group::	II
EMS-Number:	F-E,S-D
Marine pollutant:	No
Proper shipping name:	FLAMMABLE LIQUID, N.O.S. (ETHYL ACETATE, ISOPROPANOL (ISOPROPYL ALCOHOL))
Lufttransport ICAO-TI und IATA-DGR:
ICAO/IATA Class:	3
UN Number:	1993
Label:	3
Packaging group::	II
Proper shipping name:	FLAMMABLE LIQUID, N.O.S. (ETHYL ACETATE, ISOPROPANOL (ISOPROPYL ALCOHOL))
Remarks:	Packing Instructions:
	For Limited Quantities: Y305 (Max Net Qty/Pkg: 1 l)
	Passenger and Cargo Aircraft: 305 (Max Net Qty/Pkg: 5 l)
	Cargo Aircraft only: 307 (Max Net Qty/Pkg: 60 l)

Markings according to EC guidelines for Ethyl Acetate:
´The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous Materials

Risk phrases:
11 Highly flammable.
20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
36 Irritating to eyes.
68/20/21/22 Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed.
66 Repeated exposure may cause skin dryness or cracking.
67 Vapours may cause drowsiness and dizziness.

Safety phrases:
7 Keep container tightly closed.
16 Keep away from sources of ignition - No smoking.
24/25 Avoid contact with skin and eyes.
36/37 Wear suitable protective clothing and gloves.
51 Use only in well-ventilated areas.

National regulations:

Information about limitation of use:
Restrictions on juvenile employment must be observed.
Employment restrictions concerning pregnant and lactating women must be observed.

Technical guidance (air):
C l a s s  S h a r e  i n %
I                   3.5
NK                   96.5

Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.