Phenol

Information pertaining to particular dangers for man and environment:
R 23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
R 34 Causes burns.
R 48/20/21/22 Harmful: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed.
R 68 Possible risk of irreversible effects.

Classification system for Phenol:
The classification was made according to the latest editions of the EU-lists, and expanded using company data and specialized literature.

Chemical characterization	for Phenol, Carbolic acid:
CAS No. Description:	108-95-2 phenol, pure
Identification number(s):
EINECS Number:	203-632-7
EU Number:	604-001-00-2

General Information for Phenol, Carbolic acid:
Form:	Liquid or solid (depending on ambient temperature) liquid (above 40.9 °C)
Colour:	Colourless, Whitish
Odour:	Pungent, Penetrating
Change in condition
Melting point/Melting range:	40.9°C
Boiling point/Boiling range:	181.9°C (DIN 51 751) at 1013 hPa
Flash point:	81°C (DIN EN 22 71)
Flammability (solid, gaseous)	Product is not flammable.
Ignition temperature:	595°C (DIN 51 794)
Danger of explosion:	Product is not explosive. However, formation of explosive air/vapour mixtures are possible.
Explosion limits:
Lower:	1.3 Vol %
Upper:	9 Vol %
Vapour pressure at 20°C:	0.3 hPa at 50 °C 3 hPa
Density at 20°C:	1.0576 g/cm³
Vapour density at 20°C:	3.24 g/cm³
Solubility in / Miscibility with Water:	82 g/l
pH-value at 20°C:	4-5
Segregation coefficient (n-octanol/water):	1.46 log POW (CPC)

Land transport ADR/RID (cross-border)for Phenol:
ADR/RID class:	6.1 (T1) Toxic substances.
Danger code (Kemler):	60
UN-Number:	2312
Packaging group:	II
Label:	6.1
Description of goods:	Phenol, molten
Limited quantities (LQ)	LQ7
Transport category	3
Tunnel restriction code	E
Remarks:	Limited quantities: none Phenol, solid is assigned to UN 1671 zu. ADR Code (T2), class 6.1, PG II. Special Provision 279 Special provision 279: The substance is assigned to this classification or packing group based on human experience rather than the strict application criteria set out in the ADR. Limited Quantity: 1 kg inner packing, 4 kg pachaging unit
Maritime transport IMDG:
IMDG Class:	6.1
UN Number:	2312
Label:	6.1
Packaging group::	II
EMS-Number:	F-A,S-A
Marine pollutant:	No
Proper shipping name:	PHENOL, MOLTEN
Remarks:	Phenol, solid is assigned to UN 1671, class 6.1 PG II; Special Provision 279, EmS: F-A, S-A Special provision 279: The substance is assigned to this classification or packing group based on human experience rather than the strict application criteria set out in this Code.
Lufttransport ICAO-TI und IATA-DGR:
ICAO/IATA Class:	6.1
UN Number:	2312
Label:	6.1
Packaging group::	II
Proper shipping name:	PHENOL, MOLTEN
Remarks:	Forbidden for passenger and cargo aircraft.
	Phenol solid is assigned to UN 1671, class 6.1, PG II, Special Provision A 113. Packing instructions as follows:
	Special provision A 113: The substance is assigned to this classification or packing group based on
	human experience rather than the strict application criteria set out in these Regulations. Packing Instructions: For Limited Quantities: Y613 (Max Net Qty/Pkg: 1,0 kg) Passenger and Cargo Aircraft: 823 (Max Net Qty/Pkg: 25 kg) Cargo Aircraft only: 615(Max Net Qty/Pkg: 100 kg)

Markings according to EC guidelines for Phenol:
The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous Materials

Hazard-determining components of labelling:
Etidronic acid
phosphorous acid

Risk phrases:
23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
34 Causes burns.
48/20/21/22 Harmful: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed.
68 Possible risk of irreversible effects.


Safety phrases:
41 Risk of 1/2 Keep locked up and out of the reach of children.
24/25 Avoid contact with skin and eyes.
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
28 After contact with skin, wash immediately with plenty of soap and water, and also with polyethylene-glycol 400, if possible.
36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

National regulations:

Information about limitation of use:
Restrictions on juvenile employment must be observed.
Employment restrictions concerning pregnant and lactating women must be observed.

Water hazard class: Water hazard class 2 (Assessment by list): hazardous for water.